Chemistry
School of Mathematics & Physical Sciences

Prof Carl Redshaw

BSc (Newcastle), PhD (Newcastle)

Professor Carl Redshaw

Professor of Inorganic Materials Chemistry

Chemistry

  • Profile
  • Teaching
  • Research
  • Key publications

Profile

I received my BSc/PhD from Newcastle University, was a Welch Fellow at the University of Texas, Austin, and a postdoctoral fellow with the late Sir G. Wilkinson at Imperial College, and at the IRC Durham. Following a further stint at IC, I was awarded a Leverhulme Fellowship and moved to UEA as a lecturer (1999), Senior Lecturer (2007) and Reader (2009). I was appointed Professor of Inorganic Materials in Hull in 2012. I have many links with the Far East, and have been a Visiting Professor at the Shanghai Institute of Organic Chemistry (SIOC), The Institute of Chemistry, Chinese Academy of Sciences, Beijing (ICCAS), Guest Professor at Sichuan Normal University in Chengdu, and am currently Guest Professor at Northwest University in Xi'an http://chem.nwu.edu.cn/teacher.php?id=274.

Teaching

Teaching interests

  • Coordination chemistry
  • Organometallic chemistry

Lectures courses

  • Advanced Organometallic Chemistry

Laboratory classes

  • 3rd year Advanced Inorganic Laboratory Class

Research

Research theme and group: Materials Chemistry

Research interests

  • Coordination chemistry
  • Macrocyclic chemistry
  • Catalysis

My research group uses coordination chemistry to tackle a number of issues including MOFs for H2/CO2 storage and the use of metal agents against Cancers.

We are also interested in coordination chemistry of macrocycles, as well as synthesising new catalysts for olefin polymerization and biodegradable polymer production.

Key publications

Selected publications

  • Metallocalixarene catalysts: a-olefin polymerisation and ROP of cyclic esters. C. Redshaw, Dalton Trans. 2016, 45, 9018 – 9030. Doi: 10.1039/C6DT01529H
  • Synthesis, Crystal Structure and Cytotoxicity Studies of p-Sulfonatocalix[4]arene Lanthanide Complexes. D. M. Miller-Shakesby, B. P. Burke, S. Nigam, G. J. Stasiuk, T. J. Prior, S. J. Archibald and C. Redshaw, Cryst. Eng. Comm. 2016, 18, 4977-4987. Doi: 10.1039/C6CE00209A
  • Functionalization of pyrene to Advanced Luminescence Materials - A review of Methodology. X. Feng, T. Yamato, J. -Y. Hu and C. Redshaw. Chem. Eur. J. 2016, 22, 11898-11916. Doi: 10.1002/chem.201600465
  • Vanadium(V) Oxo and Imido calix[8]arene complexes: Synthesis, structural studies and ethylene homo-(co-)polymerization capability. C. Redshaw, M. J. Walton, D. S. Lee, C. Jiang, and M. R.J. Elsegood and K. Michiue, Chem. Eur. J. 2015, 21, 5199-5210. Doi: 10.1002/chem.201406084
  • Highly Selective and Immortal Magnesium Calixarene Complexes for Ring Opening Polymerization of rac-Lactide. M. J. Walton, S. J. Lancaster, and C. Redshaw. Chem.Cat.Chem. 2014, 6, 1892-1898.VIP status and Front cover. Doi: 10.1002/cctc.201402041
  • Bi- and tri-dentate imino-based iron & cobalt complex pre-catalysts for ethylene oligo-/polymerization. J. Ma, C. Feng, S. Wang, K.-Q. Zhao, W.-H. Sun, C. Redshaw and G.A. Solan, Inorg. Chem. Frontiers, 2014, 1, 14-34 (Front cover for the first issue of the first volume). Doi: 10.1039/C3QI00028A

Full publication list

2016

  • Reduction of diphenylacetylene using Al powder in the presence of noble metal catalysts in water. U. Rayhan, Z. Kowser, C. Redshaw and T. Yamato, Tetrahedron 2016, 72, 6943-6947.
  • A ratiometric Al3+ ion probe based on the coumarin-quinoline FRET system. Q. Zhu, L. Li, L. Mu, X. Zeng, C. Redshaw and G. Wei, Journal of Photochemistry and Photobiology A: Chemistry 2016, 238, 217-224.
  • A novel fluorescence “on–off–on” chemosensor for Hg2+ via a water-assistant blocking heavy atom effect. C. Wu, J.-L. Zhao, X. -K. Jiang, C. -Z. Wang, X. -L. Ni, X. Zeng, C. Redshaw and T. Yamato, Dalton Trans. 2016, 45, 14948-14953.
  • An unprecedented photochemical reaction for anthracene-containing derivatives. J. -L. Zhao, X. -k. Jiang, C. Wu, C. -Z. Wang, X. Zeng, C. Redshaw and T. Yamato, ChemPhysChem. 2016, Version of Record online : 5 SEP 2016, DOI: 10.1002/cphc.201600783.
  • Supramolecular Assemblies Constructed from Inverted Cucurbit[7]uril and Lanthanide Cations: Synthesis, structure and sorption properties. Q. Li, S. -C. Qiu, Y. -Q. Zhang, S. -F. Xue, Z. Tao, T. J. Prior, C. Redshaw, X. Xiao, Q. -J. Zhu, RSC Adv. 2016, 6, 77805-77810.
  • “Janus” calixarenes: double–sided molecular linkers for facile, multi-anchor point, multi-functional, surface modification. J. P. Buttress, D. P. Day, J. Courtney, E. J. Lawrence, D. L. Hughes, A. Crossley, S. E. Matthews, P. C. Bulman Page, C. Redshaw and G. G. Wildgoose, Langmuir.  2016, 32, 7806-7813.
  • [275] Click-modified hexahomotrioxacalix[3]arenes as fluorometric and colorimetric dual-modal chemosensor for 2,4,6-trinitrophenol. C.  Wu; J. -L. Zhao; X. -K. Jiang; X. -L. Ni, X. Zeng, C. Redshaw,  T. Yamato, Analytica Chimica Acta, 2016, 936, 216-221.
  • Synthesis and evaluation of a novel fluorescent sensor based on hexahomotrioxacalix[3]arene for Zn(Ⅱ) and Cd(Ⅱ). X.-K. Jiang, Y. Ikejiri, C.-C. Jin, C. Wu, J.-L. Zhao, X.-L. Ni, X. Zeng, C. Redshaw  and T. Yamato, Tetrahedron 2016,72,  4854-4858.
  • Structure and emission studies of Schiff-base [2+2] macrocycles derived from 2,2/-oxydianiline and the ROP capability of their organoaluminium complexes.W. Yang, K.-Q. Zhao, T. J. Prior, D. L. Hughes, A. Arbaoui, T. Bian, Y. Chao, M. R. J. Elsegood and C. Redshaw, Dalton Trans. 2016, 45, 11990-12005.
  • Extended π-conjugated pyrene derivatives: structural, photophysical and electrochemical properties. X. Feng, N. Seto, C.-Z. Wang, T. Matsumoto, J. Tanaka, M. R. J. Elsegood, L. Horsburgh, C. Redshaw and T. Yamato, Chem. Select 2016, 1, 1926-1932.
  • Synthesis, structural properties, electrophilic substitution reactions and DFT computational studies of calix[3]benzofurans. M. M. Islam, T. Akther, Y. Ikejiri, T. Matsumoto, J. Tanaka, S. Rahman, P. E. Georghiou, D. L. Hughes, C. Redshaw and T. Yamato. RSC Advances 2016, 6, 50808-50817.
  • Molecular Catalysis for Precise Olefin Polymerization and ROP 2015. C. Redshaw, Catalysts 2016, 6, 53.
  • Functionalization of pyrene to Advanced Luminescence Materials - A review of Methodology. X. Feng, T. Yamato, J. -Y. Hu and C. Redshaw. Chem. Eur. J. 2016, 22, 11898-11916.
  • Thiacalix[4]arene derivatives bearing imidazole units: a ditopic hard/soft receptor for Na+//Ag+/ and K+//Ag+/ with allosteric effect and a reusable extractant for dichromate anions. J.-L. Zhao, C. Wu, X. Zeng, S. Rahman, P. E. Georghiou, M. R. J. Elsegood, T. G. Warwick, C. Redshaw, S. J. Teat and T. YamatoChemistry Select 2016, 1, 1541-1547.
  • Synthesis, Crystal Structure and Cytotoxicity Studies of p-Sulfonatocalix[4]arene Lanthanide Complexes. D. M. Miller-Shakesby, B. P. Burke, S. Nigam, G. J. Stasiuk, T. J. Prior, S. J. Archibald and C. Redshaw, Cryst. Eng. Comm. 2016, 18, 4977-4987.
  • Interaction of a Symmetrical α,α',δ,δ'-Tetramethyl-cucurbit[6]uril with Ln3+: Potential for the Isolation of Lanthanides. B. Yang,Z.-Z. Gao,J.-H. Lu,Q.-J. Zhu, S.-F. Xue, Z. Tao, T. J. Prior, C. Redshaw and X. Xiao. Cryst. Eng. Comm. 2016, 18, 5028-5035.
  • Demethylation of 5,n-di-tert-butyl-8,n-dimethoxy[2.n] metacyclophane-1-ynes with BBr3 to afford novel [n]benzofuranophanes. T. Akther, M. M. Islam, T. Matsumoto, J. Tanaka, X.   Feng, C.  Redshaw and T. Yamato, Journal of Molecular Structure. 2016, 1122, 247-255.
  • Synthesis and structures of O-anthrylmethyl-substituted hexahomotrioxacalix[3]arenes. X.-K. Jiang, Y. Ikejiri, X.-L. Ni, X. Zeng, C. Redshaw and T. Yamato. J. Mol. Struct. 2016, 1120, 274-280.
  • Manganese coordination chemistry of bis(imino)phenoxide derived [2 + 2] Schiff-base macrocyclic ligands. W. Yang, K. -Q. Zhao, B. -Q. Wang, C. Redshaw, M. R. J. Elsegood, J. -L. Zhao and T. Yamato, Dalton Trans. 2016, 45, 226-236.
  • Metallocalixarene catalysts: a-olefin polymerisation and ROP of cyclic esters. C. Redshaw, Dalton Trans. 2016, 45, 9018 – 9030.
  • A Pyrene-functional triazole-linked hexahomotrioxacalix[3]arene as a fluorescent chemosensor for Zn2+ ions. C. Wu, Y. Ikejiri, J. -L. Zhao, X. -K. Jiang. X. -L. Ni, X. Zeng, C. Redshaw, Sensors & Actuators: B. Chemical. 2016, 228, 480-485.
  • Vanadyl phenolate complexes for ring opening homo- and co-polymerisation of e-caprolactone, L-lactide and rac-lactide. F. Ge, Y. Dan, Y. Al-Khafaji, T. J. Prior, L. Jiang, M. R. J. Elsegood and C. Redshaw, RSC Adv. 2016, 6, 4792-4802.
  • A Rare and Exclusive Endoperoxide Photoproduct Derived from Thiacalix[4]arene Crown-shaped Derivative Bearing 9,10–Substituted Anthracene Moiety. J. -L. Zhao, C. Wu, X. Zeng, H. Tomiyasu, M. R. J. Elsegood, C. Redshaw and T. Yamato, Chem. Asian J. 2016, 11, 1606-1612.
  • A single chemosensor for multiple analytes: Fluorogenic and ratiometric absorbance detection of Zn2+, Mg2+ and F-, and its cell imaging, L. Li, Y. Shen, Y. -H. Zhao, L. Mu, X. Zeng, C. Redshaw  and G. Wei, Sensors and Actuators B, Chemical, 2016, 226, 279-288.

2015

  • Molybdenum(VI) imido complexes derived from chelating phenols: synthesis, characterization and ɛ-caprolactone ROP capability. Y. Al-Khafaji, T. J. Prior, M. R. J. Elsegood and C. Redshaw, Catalysts 2015, 5, 1928-1947.
  • A pyrene-armed hexahomotrioxacalix[3]arene as a multi-sensor via synergistic and demetallation effects. C. Wu, C. -C. Jin, M. Fukuda, X. Jiang, X. -L. Ni, X. Zeng, C. Redshaw and T. Yamato, Tetrahedron, 2015, 71, 9593-9597.
  • Para-Selective C–H Amidation of Simple Arenes with Nitriles as the Amino Source. S.-K. Xiang, J.-M. Li, H. Heung, C. Feng, H.-L. Ni, X.–Z. Chen, B.-Q. Wang, K. -Q. Zhao, P. Hu and C. Redshaw Advanced Synthesis and Catalysis, 2015, 357, 3435-3440.
  • Characterization of the aggregation-induced enhanced emission of N,N-bis(4-methoxysalicylide) benzene-1,4-diamine, F. Wu, G. Xu, X. Zeng, L. Mu, C. Redshaw and . Wei, J. Fluoresc 2015, 25, 1183-1189.
  • Synthesis, crystal structure and complexation behaviour study of an efficient Cu2+ ratiometric fluorescent chemosensor based on thiacalix[4]arene. J.-L. Zhao, H. Tomiyasu, C. Wu, H. Cong, X. Zeng, S. Rahman, P. E. Georghiou, D. L. Hughes, C. Redshaw and T. Yamato, Tetrahedron, 2015, 71, 8521-8527.
  • Regio-selective substitution at the 1,3- and 6,8-positions of pyrene for the construction of small dipolar molecules. X. Feng, H. Tomiyasu, J.-Y. Hu, X.-F. Wei, C. Redshaw, M.R.J. Elsegood, L. Horsburgh, S. Teat and T. Yamato, Org. Lett. Published on the web 5.10.15
  • Vanadium(V) tetra-phenolate complexes: Synthesis, structural studies and ethylene homo-(co-)polymerization capability. C. Redshaw, M. J. Walton, M.R.J. Elsegood, T. J. Prior and K. Michiue, submitted to RSC Advances, Published on the web 8.10.15.
  • Molybdenum complexes derived from the oxydianiline [(2-NH2C6H4)2O]: Synthesis, characterization and ε-caprolactone ROP capability. W. Yang, Q.-K. Zhao, C. Redshaw, and M.R.J. Elsegood, Dalton Trans, 2015, 44, 13133-13140.
  • Synthesis and conformational studies of novel chiral macrocyclic [1.1.1]metacyclophanes containing benzofuran rings. Md. M. Islam, T. Hirotsugu, T. Matsumoto, J. Tanaka, C. Redshaw and T. Yamato, Org. Biomol. Chem. 2015, 13, 9055-9064.
  • Solvent effect and fluorescence response of the 7-tert-butylpyrene-dipicolyl amine linkage for the selective and sensitive response toward Zn(II) and Cd(II) ions. Z. Kowser, H. Tomiyasu, X. Jiang, C. Redshaw and T. Yamato, New J. Chem. 2015, 39, 4055-4062.
  • Synthesis and conformational studies of calixarene analogue chiral macrocyclic [3.3.1]metacyclophanes. Md. M. Islam, T. Hirotsugu, P. Thuery, T. Matsumoto, J. Tanaka, M. R.J. Elsegood, C. Redshaw and T. Yamato, J, Mol. Struct. 2015, 1098, 47-54.
  • Mono-and Tetra-nuclear copper complexes bearing bis(imino)phenoxide derived ligands: catalytic evaluation for benzene oxidation and ROP of -caprolactone. X. Wang, Q.-K. Zhao, M.R.J. Elsegood, T.J. Prior,c X. Liu, W. Li, S. Sanz, E. K. Brechin and C. Redshaw, RSC Adv. 2015, 5, 57414 - 57424.
  • Vanadyl calix[6]arene complexes: Synthesis, structural studies and ethylene homo-(co-)polymerization capability. C. Redshaw, M. Walton, K. Michiue, Y. Chao, A. Walton, P. Elo, V. Sumerin, C. Jiang and M. R.J. Elsegood, Dalton Trans. 2015, 44, 12292 - 12303.
  • The first study about the relationship between the extractability of thiacalix[4]arene derivatives and the position of the coordination binding sites. J.-L. Zhao, H. Tomiyasu,  X.-L. Ni,   X. Zeng,  M. R. J. Elsegood,   C. Redshaw,   S. Rahman,   P. E. Georghiou,   S. J. Teat and   T. Yamato,   Org. Biomol. Chem. 2015, 13, 3476-3483.
  • Influence of substituent position on thermal properties, photoluminescence and morphology of pyrene-fluorene derivatives. X. Feng, J.-Y. Hu, X.-F. Wei, T. Yamato and C.  Redshaw, J. Mol. Struct. 2015, 1086, 216-222.
  • A Uracil nitroso amine based colorimetric sensor for the detection of Cu2+ ions from a 100 % aqueous environment and its practical applications. S. R. Patil, J. P. Nandre, S. K. Sahoo, M. Devi, C. P. Pradeep, Y. Fabiao, L. Chen, C. Redshaw, P. P. Mahulikar and U. D. Patil, RSC Advances. 2015, 5, 21464-21470.
  • Tetraphenolate niobium and tantalum complexes for the ring opening polymerization of ɛ-caprolactone. Y. Al-Khafaji, X. Sun, T.J. Prior, M. R.J. Elsegood, and C. Redshaw, Dalton Trans. 2015, 44, 12349 - 12356 (open access).
  • Vanadium(V) Oxo and Imido calix[8]arene complexes: Synthesis, structural studies and ethylene homo-(co-)polymerization capability. C. Redshaw, M. J. Walton, D. S. Lee, C. Jiang, and M. R.J. Elsegood and K. Michiue, Chem. Eur. J. 2015, 21, 5199-5210.
  • Synthesis of a ditopic homooxacalix[3]arene for fluorescence enhanced detection of heavy and transition metal ions. X.-L. Ni, Y. Wu, C.-C. Jin, C. Redshaw, T. Yamato, Supramolchem. 2015, 27, 501-507.
  • Iron(III) bromide catalyzed bromination of 2-tert-butylpyrene and corresponding positions-dependent aryl-functionalized pyrene derivatives. X. Feng, J.-Y. Hu, H. Tomiyasu, Z. Tao, C.  Redshaw, M.R.J. Elsegood, L. Horsburgh, S.J. Teat, X.-F. Wei and T.Yamato.  RSC Advances, 2015, 5, 8835-8848.
  • Positive and negative allosteric effects for thiacalix[4]arene-based receptors bearing urea and crown–ether moieties. H. Tomiyasu, J.-L. Zhao, X.-L. Ni, X. Zeng, M. R. J. Elsegood, B. Jones, C. Redshaw, S. J. Teat, and T. Yamato, RSC Advances,2015, 5, 14747-14755.

2014

  • Chromium complex pre-catalysts in ethylene oligomerization/Polymerization, V. Katla, S. Du, C. Redshaw, W.-H. Sun, Review of Catalysts, 2014, 1, 1-14.
  • Zinc calixarene complexes for the Ring Opening Polymerization of Cyclic Esters. M.J. Walton, S.J. Lancaster, J. A. Wright, M.R.J. Elsegood and C. Redshaw, Dalton Trans. 2014, 43, 18001-18809.
  • Synthesis and evaluation of a novel ionophore based on a thiacalix[4]arene derivative bearing imidazole units. J.-L. Zhao, H. Tomiyasu, X.-L. Ni, X. Zeng, M. R. J. Elsegood, C. Redshaw and T. Yamato, New J. Chem. 2014, 38, 6041-6049.
  • A Reversible and Visible Colorimetric/Fluorescent Chemosensor for Al3+ and F- ions with a Large Stoke’s Shift. Y.-H. Zhao, X. Zeng, L. Mu, J. Li, C. Redshaw and G. Wei, Sensors and Actuators B, Chemical. 2014, 204, 450-458.
  • A convenient tandem one-pot synthesis of donor-acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene. C. Feng, X.-L. Tian, J. Zhou, S.-K, Xiang, W.-H. Yu, B.-Q. Wang, P. Hu, C. Redshaw and K.-Q. Zhao, submitted to Org. Biomol Chem. 2014, 12, 6977-6981.
  • Tri- and tetra-dentate  imine vanadyl complexes: Synthesis, structure and ethylene polymerization/ring opening polymerization capability. J. Ma, K.-Q. Zhao, M. J. Walton, J. A. Wright, D. L. Hughes, M. R.J. Elsegood, K. Michiue, X. Sun and C. Redshaw,  Dalton Trans. 2014, 43, 16698-16706.
  • Positive allosteric binding behaviour of pyrene appended triazole modified thiacalix[4]arene based fluorescent receptors. H. Tomiyasu, N. Shigyo, X.-L. Ni, X. Zeng, C. Redshaw and T. Yamato, Tetrahedron. 2014, 70, 7893-7899.
  • The amidine based colorimetric sensor for Fe3+, Fe2+ and Cu2+ in aqueous medium. J. Nandre, S. Patil, P. Patil, S. K. Sahoo, C. Redshaw, P. Mahulikar and U. Patil, J. Fluoresc. 2014, 24, 1563-1570.
  • Rhodamine-Triazine Based Probe for Cu2+ in Aqueous Media and Living Cells, Y. Zhang, X. Zeng, L. Mu, Y. Chen, J.-X. Zhang, C. Redshaw, G. Wei, Sensors and Actuators B, 2014, 204, 24-30.
  • A novel fluorescent “turn-on” chemosensor for nanomolar detection of Fe(III) from aqueous solution and its application in living cells imaging. J. P. Nandre, S. R. Patil, V. S. Patil, F. Yu,  L. Chen, S. K. Sahoo, T. J. Prior, C. Redshaw, P. P. Mahulikar, U. D. Patil. Biosensors and Bioelectronics, 2014, 61, 612-617.
  • Ethyleneglycol Tungsten Complexes of calix[6 and 8]arenes: Synthesis, Characterization and ROP of -caprolactone. Y. Li, K.-Q. Zhao, C. Feng, M. R.J. Elsegood, T. J. Prior, X. Sun, and C. Redshaw, Dalton Trans. 2014, 43, 13612-13619.
  • Organoaluminium complexes of o-,m-,p-anisidines: Synthesis, structural studies and ROP of -caprolactone. Y. Li, K.-Q. Zhao, M. R.J. Elsegood, T. J. Prior, X. Sun, S. Mo and C. Redshaw, Cat. Sci & Tech., 2014, 4, 3025-3031.
  • A study of allosteric binding behaviour of a 1,3-alternate thiacalix[4]arene-based receptor using fluorescence signal. H. Tomiyasu,   C.-C. Jin,   X.-L. Ni,   X. Zeng,   C. Redshaw and   T. Yamato, Org. Biomol. Chem., 2014, 12, 4917-4923.
  • Direct evidence of a blocking heavy atom effect on the water-assisted fluorescence enhancement detection of Hg2+ based on a ratiometric chemosensor.   X.-N. Ni, Y. Wu, C. Redshaw and T. Yamato, Dalton Trans. 2014, 43, 12633-12638.
  • Synthesis and inclusion behaviour of a heterotritopic receptor based on hexahomotrioxacalix[3]arene. C.C. Jin, H. Cong, X.-L. Ni, X. Zeng, C.Redshaw and T. Yamato, RSC Advances, 2014, 4, 31469-31475.
  • Synthesis, characterization and ethylene polymerization behaviour of binuclear nickel halides bearing 4,5,9,10-tetra(arylimino)pyrenylidenes. Q. Xing, K. Song, T. Liang, Q. Liu, W.-H. Sun and C. Redshaw, Dalton Trans. 2014, 43, 7830-7837.
  • Vanadyl complexes bearing bi-dentate phenoxyimine ligands: Synthesis, structural studies and ethylene polymerization capability. J. Ma, K.-Q. Zhao, M. Walton, J. A. Wright, J. W.A. Frese, M.R.J. Elsegood, Q. Xing, W.-H. Sun and C. Redshaw. Dalton Trans. 2014, 43, 8300-8310.
  • Highly Selective and Immortal Magnesium Calixarene Complexes for Ring Opening Polymerization of rac-Lactide. M. J. Walton, S. J. Lancaster, and C. Redshaw. Chem.Cat.Chem. 2014, 6, 1892-1898.VIP status and Front cover.
  • Biphenyl-bridged 6-(1-aryliminoethyl)-2-iminopyridylcobalt complexes: Synthesis, characterization and ethylene polymerization behaviour. Organometallics, 2014, 33, 1382-1388.
  • Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands with a pendant arm: NMR and EPRspectroscopic studies of the reaction intermediates. J. Ma, K.-Q. Zhao, I. E. Soshnikov, N. V. Semikolenova, V. A. Zakharov, K. P. Bryliakov, C. Redshaw and E. P. Talsi, Organometallics, 2014, 33, 1431-1439.
  • 2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino}-3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization and investigation of their catalytic behaviour. Q. Liu, W.  Zhang, D. Jia, X.  Hao,  C. Redshaw,  W.-H.  Sun, Appl. Cat. A., 2014, 475, 195-202.
  • Recent progress on nickel-based systems for ethylene oligo-/polymerization catalysis. S. Wang, W.-H. Sun and C. Redshaw, J. Organomet. Chem. 2014, 751, 717-741.
  • Dichloropalladium complexes ligated by 4,5-bis(arylimino)pyrenylidenes: Synthesis, characterization, and catalytic behaviour towards Heck-reaction. K. Song, S. Kong, Q. Liu. W.-H. Sun and C, Redshaw, J. Organomet. Chem. 2014, 751, 453-457.
  • Synthesis and characterization of 2-(2-benzhydrylnaphthyliminomethyl)pyridylnickel halides: formation of branched polyethylene. E. Yue, Q. Xing, L. Zhang, Q. Shi, X.-P. Cao, L. Wang, C. Redshaw and W.-H. Sun,  Dalton Trans, 2014, 43, 3339-3346.
  • Half-titanocene 5-t-butyl-2-(1-(arylimino)methyl)quinolin-8-olate chlorides: Synthesis, characterization and ethylene (co-)polymerization. Q. Yan, W. Yang, L. Chen, L. Wang, C. Redshaw, W.-H. Sun J. Organomet. Chem. 2014, 753, 34-41.
  • Pillared 2-D metal-organic frameworks based on a lower-rim acid appended calix[4]arene" C. Redshaw, O. Rowe, M.R.J. Elsegood, L. Horsburgh and S.J. Teat, Cryst. Growth & Design, 2014, 14, 270-277.
  • Dialkylaluminium 2-imidazolylphenolates: Synthesis, characterization and ring-opening polymerization behaviour towards lactides. W. Zhang, Y. Wang, L. Wang, C. Redshaw, W.-H. Sun, J. Organomet. Chem. 2014, 750, 65-73.
  • Zinc 2-((2-(benzoimidazol-2-yl)quinolin-8-ylimino)methyl)phenolates: Synthesis, characterization and photoluminescence behaviour.  L.Li, X. Zhang, W. Zhang, W. Li, W.-H. Sun and C. Redshaw. Spectrochimica Acta A, Mol. Biomol. Spec. 2014, 118, 1047-1055.
  • Bi- and tri-dentate imino-based iron & cobalt complex pre-catalysts for ethylene oligo-/polymerization. J. Ma, C. Feng, S. Wang, K.-Q. Zhao, W.-H. Sun , C. Redshaw and G.A. Solan, Inorg. Chem. Frontiers, 2014, 1, 14-34 (Front cover for the first issue of the first volume).
  • Beneficial influence of nanocarbon on the aryliminopyridylnickel chloride catalyzed ethylene
    polymerization. L. Zhang, E. Yue, B. Liu, P. Serp, C. Redshaw, W.-H. Sun and J. Durand, Cat. Comm., 2014, 43, 227-230.
  • 2-(1-(2-Benzhydrylnaphthylimino)ethyl)pyridylnickel halides: synthesis, characterization, and ethylene polymerization behaviour. E. Yue, L. Zhang, Q. Xing, X.-P. Cao, X. Hao, C. Redshaw and W.-H. Sun, Dalton Trans., 2014, 43, 423-431. Hot Article, back cover and open access.

2013

  • Synthesis, characterization and ethylene polymerization behaviour of binuclear iron complexes bearing N,N/-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines, Q. Xing, T. Zhao, Y. Qiao, L. Wang, C. Redshaw, and W.-H. Sun, RSC Advances, 2013, 3, 26184-26193.
  • Synthesis and photophysical properties of novel butterfly-shaped blue emitters based on pyrene. X. Feng, J.-Y. Hu, N. Seto, H. Tomiyasu, M. R. J. Elsegood, C. Redshaw and T. Yamato, Org. Biomol. Chem. 2013, 11, 8366-8374.
  • Rhenium(I) phenanthrolines bearing electron withdrawing CF3 substituents: synthesis, characterization and  biological evaluation. C. Redshaw, S. Watkins, S. M, Humphrey, P. C. Bulman Page, S. Ashby, Y. Chao, C. J. Herbert  and A. Mueller, RSC Advances 2013, 3, 23963-23966.
  • Unsymmetrical α-Diiminonickel Bromide complexes: Synthesis, characterization and investigation of their catalytic behaviour toward ethylene. D. Jia, W. Zhang, W. Liu, L. Wang, C. Redshaw and W.-H. Sun Cat. Sci & Tech. 2013, 3, 2737-2745.
  • 2-(1-Aryliminoethyl)cycloheptapyridylpalladium chlorides: Synthesis, characterization and the use in the Heck-reaction. B. Ye, L. Wang, X. Hu, C. Redshaw and W.-H. Sun, Inorg. Chimica Acta, 2013, 407, 281-288.
  • Tetraphenylene-Triphenylene Oligomers with an Aggregation-induced Emission effect and Discotic Columnar Mesophase. W.-H. Yu, C. Chen, B.-Q. Wang, C. Redshaw and K.-Q. Zhao, RSC Advances, 2013, 3, 14099-14105.
  • Tri-substituted hexahomotrioxacalix[3]arene derivatives bearing imidazole units: synthesis and extraction properties for cations and chromate anions. X.-L. Ni, C.-C. Jin, X.-K. Jiang, M. Takimoto, S. Rahman, X. Zeng, D. L. Hughes, C. Redshaw and T. Yamato, Org. Biomol. Chem. 2013, 11, 5435-5442.
  • Synthesis, Structural and Photophysical Properties of the First Member of New Class of Pyrene Based [4]Helicenes. J.-Y. Hu, X. Feng, A. Paudel, H. Tomiyasu, U. Rayhan, P. Thuéry, M. R. J. Elsegood, C. Redshaw and T. Yamato, Eur. J. Org. Chem. 2013, 5829-5837.
  • An efficient approach to the synthesis of novel pyrene-fused azaacenes. X. Feng, F. Iwanaga, J.-Y. Hu, H. Tomiyasu, C. Redshaw, M. R. J. Elsegood and T. Yamato, Org. Lett. 2013, 15, 3594-3597.
  • Synthesis of Triphenylene Discotic Liquid Crystals Possessing Nine Alkyl Chains: Influence of Molecular Symmetry and Chain Length on Mesomorphism. L. Xiao, H. Wang, C. Redshaw, Q.-K. Zhao. Molecular Crystals and Liquid Crystals. 2013, 577, 25-35.
  • Blue-Emitting Butterfly-Shaped 1,3,5,9-Tetraarylpyrenes: Synthesis, Crystal Structures and Photophysical Properties. X. Feng, H. Xing, I. Jian-Yong, S. Fumitaka, T. Nobuyuki, C. Redshaw, M.R.J. Elsegood, T. Yamato, Org. Lett. 2013, 15, 1318-1321.
  • Mono-Disperse Triphenylene Discotic Liquid Crystal Oligomers synthesized by Click Chemistry. Y.-F. Bai, K.-Q. Zhao, P. Hu, B.-Q. Wang and C. Redshaw, Curr. Org. Chem. 2013, 17, 871 – 885.
  • Synthesis and fluorescence emission properties of 1,3,6,8-tetraarylpyrenes. J.-Y. Hu, X. Feng, H. Tomiyasu, N. Seto, U. Rayhan, M. R.J. Elsegood, C. Redshaw, T. Yamato,  J. Mol. Structure, 2013, 1047, 194 – 203.
  • Highly active, thermally stable, ethylene polymerization pre-catalysts based on Niobium and Tantalum imine systems. C. Redshaw, M. Walton, L. Clowes, D. L. Hughes, A.-M. Fuller, Y. Chao, A. Walton, V. Sumerin, P. Elo, I. Soshnikov, W. Zhao and W.-H. Sun. Chem. Eur. J. 2013, 19, 8884-8899.
  • Nickel complex pre-catalysts in ethylene polymerization: new approaches to elastomeric materials. R. Gao, W.-H. Sun and C. Redshaw, Cat. Sci & Tech. 2013, 3, 1172 - 1179.
  • Methylene-bridged bimetallic α-diimino nickel(II) complexes: synthesis and high efficiency in ethylene polymerization. S. Kong, K. Song, T. Liang, C.-Y. Guo, W.-H. Sun and C. Redshaw, Dalton Trans, 2013, 42, 9176 - 9187.
  • Synthesis, characterization and catalytic behaviour toward ethylene of 2-[1-(4,6-dimethyl-2- benzhydrylphenylimino)ethyl]-6-[1-(arylimino)ethyl]pyridylmetal (iron or cobalt) chlorides. S. Wang, B. Li, T. Liang, C. Redshaw, Y. Li and W.-H. Sun, Dalton Trans. 2013, 42, 9188 – 9197.
  • 2-(1-{2,6-bis[bis(4-fluorophenyl)methyl]-4-methylphenylimino}ethyl)-6-[1-(arylimino)ethyl]pyridylcobalt(II) dichlorides: synthesis, characterization and ethylene polymerization behaviour. S. Wang, W. Zhao, T. Liang, B. Li, C. Redshaw, Y. Li and W.-H. Sun. J. Organomet. Chem. 2013, 731, 78 - 84.
  • Halonickel 2,4-di-t-butyl-6-(quinolin-8-yliminomethyl)phenolates: Synthesis, Characterization and ethylene reactivity. Q-S. Shi, X. Hao, C. Redshaw, W.-H. Sun, Chinese J. of Polym. Sci. 2013, 31, 769 - 777.
  • Tailoring Iron Complexes for Ethylene Oligomerization and/or Polymerization W. Zhang, W.-H. Sun and C. Redshaw. Dalton Trans. 2013, 42, 8988 - 8997.
  • Nickel(II) complexes bearing 4,5-bis(arylimino)pyrenylidenes: Synthesis, characterization, and ethylene polymerization behaviour. K. Song, W. Yang, B. Li, Q. Liu, C. Redshaw, Y. Li and W.-H. Sun, Dalton Trans, 2013, 42, 9166 - 9175.
  • Probing the characteristics of mono- and bi-metallic (Iron or Cobalt) Complexes Bearing 2,4-di(6-iminopyridin-2-yl)-3H-benzazepines: Syntheses, characterization and reactivity towards ethylene. W.-H. Sun, J. Yu, E. Novikova, W. Zhao, X. Tang, T. Liang, and C. Redshaw, Organometallics 2013, 32, 2309 - 2318.
  • Blue-Emitting Butterfly-Shaped 1,3,5,9-Tetraarylpyrenes: Synthesis, Crystal Structures and Photophysical Properties. X. Feng, H. Xing, I. Jian-Yong, S. Fumitaka, T. Nobuyuki, C. Redshaw, M.R.J. Elsegood, T. Yamato, Org. Lett. 2013, 15, 1318 – 1321.
  • Vanadium(III) phenoxyimine complexes for ethylene or -caprolactone polymerization: mononuclear versus
    binuclear pre-catalysts. L. Clowes, M. Walton, C. Redshaw, Y. Chao, A. Walton, P. Elo, V. Sumerin and D. L. Hughes. Cat. Sci. & Tech. 2013, 3, 152-160.
  • An NBD-armed thiacalix[4]arene-derived colorimetric and fluorometric chemosensor for Ag+: a metal ligand receptor of anions. Y. Fu, L. Mu, X. Zeng, J.-L. Zhao, C. Redshaw, X.-L. Ni and T. Yamato, Dalton Trans, 2013, 42, 3552 – 3560.
  • New structural motifs in Lithium and zinc calix[4]arene chemistry. C. Redshaw, O. Rowe, D. L. Hughes, A.M. Fuller, I. Alvarado Ibarra and S. M. Humphrey, Dalton Trans. 2013, 42, 1983 - 1986.
  • Macrocycle-based metal ion complexation: a study of the lanthanide contraction effect towards hexacyclohexanocucurbit[6]uil. X. Qin, X.-L. Ni, J.-X. Hu, K. Chen, Y.-Q. Zhang, C. Redshaw, Q.-J. Zhu, S.-F. Xue and Z. Tao, Cryst. Eng. Comm. 2013, 15, 738-744.
  • Synthesis Structure and Fluorescent Properties of 2-(1H-Benzoimidazol-2-yl)quinolin-8-ols and Their Zinc Complexes. J. Xia, Z. Zhou, W. Li, H.-Q. Zhang, C. Redshaw and W.-H. Sun, Inorg. Chim. Acta 2013, 394, 569-575.
  • Pyrene-cored blue-light emitting [4]helicenes: Synthesis, crystal structures, and photophysical properties. J.-Y. Hu, A. Paudel, N. Seto, X. Feng, M. Era, T. Matsumoto, J. Tanaka, M. R. J. Elsegood, C. Redshaw and T. Yamato. Organic and Biomolecular Chemistry, 2013, 11, 2186 - 2197.
  • Highly active 8-benzoxazolyl- or 8-benzothiazolyl-2-alkylquinolinylnickel(II) complexes for ethylene dimerization and vinyl polymerization of norbornene. P. Hao, S. Song, T. Xiao, Y. Li, C. Redshaw, W.-H. Sun. Polyhedron, 2013, 52, 1138 – 1144.
  • [CdCl4]2--Induced Coordination and Self-Assembly of Lanthanide Metal Ions to Cucurbit[7]uril: Strategies for the Construction of Macrocycle Based Tubular Nanochannels. L.-L. Liang, X.-L. Ni, Y. Zhao, K. Chen, X. Xiao, Y.-Q. Zhang, C. Redshaw, Q.-J. Zhu, S.-F. Xue, and Z. Tao, Inorg. Chem. 2013, 52, 1909 – 1915.
  • Copper-free click chemistry between azides and internal alkynes for triphenylene discotic liquid crystal trimer formation. Y. –F. Bai, L. Bao, P. Hu, B. –Q. Wang, C. Redshaw and K.-Q. Zhao, Liquid Crystals 2013, 40, 97 - 105.

2012

  • Nickel bis{4,6-dibenzhydryl-2-[(arylimino)methyl]phenoxylate} complexes: Synthesis, structures, and catalytic behaviour towards ethylene and norbornene, Z. H. Zhou, X. Hao, C. Redshaw, L. Q. Chen, and W. H. Sun, Catal. Sci. Technol., 2012, 2, 1340-5. doi: 10.1039/c2cy20028g
  • Controlling the ethylene polymerization parameters in iron pre-catalysts of the type 2-[1-(2,4-dibenzhydryl-6-methylphenylimino)ethyl]-6-[1-(arylimino)ethyl] pyridyliron dichloride, W. Z. Zhao, J. G. Yu, S. J. Song, W. H. Yang, H. Liu, X. Hao, C. Redshaw, and W. H. Sun, Polymer, 2012, 53, 130-7. doi: 10.1016/j.Polymer.2011.11.024
  • 2-Aldiminophenoxytitanium chloride complexes: Synthesis, characterization, and ethylene (co-)polymerization behaviour, W. J. Zhang, Y. H. Wang, C. Redshaw, X. Hao, and W. H. Sun, J. Organomet. Chem., 2012, 715, 119-28. doi: 10.1016/j.jorganchem.2012.05.048
  • 2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behaviour, W. J. Zhang, W. B. Chai, W. H. Sun, X. Q. Hu, C. Redshaw, and X. Hao, Organometallics, 2012, 31, 5039-48. doi: 10.1021/om300388m
  • Enhancing the Activity and Thermal Stability of Iron Precatalysts Using 2-(1-{2,6-bis[bis(4-fluorophenyl)methyl]-4-methylphenylimino}ethyl)-6-[1 -(arylimino)ethyl]pyridines, W. H. Sun, W. Z. Zhao, J. G. Yu, W. J. Zhang, X. Hao, and C. Redshaw, Macromol. Chem. Phys., 2012, 213, 1266-73. doi: 10.1002/macp.201200051
  • 2-(1-Arylimino)quinolylnickel halides: Synthesis, characterization and catalytic behaviour towards ethylene, S. J. Song, T. P. F. Xiao, L. Wang, C. Redshaw, F. S. Wang, and W. H. Sun, J. Organomet. Chem., 2012, 699, 18-25. doi: 10.1016/j.jorganchem.2011.11.001
  • Tridentate ligands and beyond in group IV metal alpha-olefin homo-/co-polymerization catalysis, C. Redshaw and Y. Tang, Chem. Soc. Rev., 2012, 41, 4484-510. doi: 10.1039/c2cs35028a
  • Cellular uptake of a fluorescent vanadyl sulfonylcalix[4]arene, C. Redshaw, M. R. J. Elsegood, J. A. Wright, H. Baillie-Johnson, T. Yamato, S. De Giovanni, and A. Mueller, Chem. Commun., 2012, 48, 1129-31. doi: 10.1039/c2cc16480a
  • Cellular uptake studies of two hexanuclear, carboxylate bridged, zinc ring structures using fluorescence microscopy, C. Redshaw, M. R. J. Elsegood, J. W. A. Frese, S. Ashby, Y. M. Chao, and A. Mueller, Chem. Commun., 2012, 48, 6627-9. doi: 10.1039/c2cc32060f
  • Ditopic Receptors based on Lower- and Upper-Rim Substituted Hexahomotrioxacalix[3]arenes: Cation-Controlled Hydrogen Bonding of Anion, X. L. Ni, J. Tahara, S. Rahman, X. Zeng, D. L. Hughes, C. Redshaw, and T. Yamato, Chem.-Asian J., 2012, 7, 519-27. doi: 10.1002/asia.201100926
  • Hexahomotrioxacalix[3]arene derivatives as ionophores for molecular recognition of dopamine, serotonin and phenylethylamine, X. L. Ni, S. Rahman, S. Wang, C. C. Jin, X. Zeng, D. L. Hughes, C. Redshaw, and T. Yamato, Org. Biomol. Chem., 2012, 10, 4618-26. doi: 10.1039/c2ob25177a
  • Synthesis, characterization and ethylene polymerization behaviour of nickel dihalide complexes bearing bulky unsymmetrical alpha-diimine ligands, H. Liu, W. Z. Zhao, J. G. Yu, W. H. Yang, X. Hao, C. Redshaw, L. Q. Chen, and W. H. Sun, Catal. Sci. Technol., 2012, 2, 415-22. doi: 10.1039/c1cy00319d
  • 2-[1-(2,4-Dibenzhydryl-6-methylphenylimino)ethyl]-6-[1-(arylimino)ethyl] pyridylcobalt(II) dichlorides: Synthesis, characterization and ethylene polymerization behaviour, J. J. Lai, W. Z. Zhao, W. H. Yang, C. Redshaw, T. L. Liang, Y. W. Liu, and W. H. Sun, Polym. Chem., 2012, 3, 787-93. doi: 10.1039/c2py00590e
  • 2-[1-(2,6-Dibenzhydryl-4-methylphenylimino)ethyl]-6-[1-(arylimino)ethyl] pyridylnickel(II) halides: Synthesis, characterization and ethylene oligomerization behaviour, J. J. Lai, X. H. Hou, Y. W. Liu, C. Redshaw, and W. H. Sun, J. Organomet. Chem., 2012, 702, 52-8. doi: 10.1016/j.jorganchem.2011.12.031
  • 2-Substituted 8-(2-benzhydrylarylimino)-5,6,7-trihydroquinoline-N,N ' nickel dichlorides: Synthesis, characterization and catalytic behaviour towards ethylene, X. H. Hou, T. L. Liang, W. H. Sun, C. Redshaw, and X. Chen, J. Organomet. Chem., 2012, 708, 98-105. doi: 10.1016/j.jorganchem.2012.02.031
  • N-(5,6,7-Trihydroquinolin-8-ylidene)-2-benzhydrylbenzenaminonickel halide complexes: synthesis, characterization and catalytic behaviour towards ethylene polymerization, X. H. Hou, Z. G. Cai, X. Chen, L. Wang, C. Redshaw, and W. H. Sun, Dalton Trans., 2012, 41, 1617-23. doi: 10.1039/c1dt11766a
  • 2-[1-(2,6-dibenzhydryl-4-chlorophenylimino)ethyl]-6-[1-aryliminoethyl]py ridyl cobalt dichlorides: Synthesis, characterization and ethylene polymerization behaviour, F. He, W. Z. Zhao, X. P. Cao, T. L. Liang, C. Redshaw, and W. H. Sun, J. Organomet. Chem., 2012, 713, 209-16. doi: 10.1016/j.jorganchem.2012.05.020
  • Nickel halide complexes bearing 2-benzimidazolyl-N-arylquinoline-8-carboxamide derived ligands: Synthesis, characterization and catalytic behaviour towards ethylene oligomerization and the vinyl polymerization of norbornene, F. He, X. Hao, X. P. Cao, C. Redshaw, and W. H. Sun, J. Organomet. Chem., 2012, 712, 46-51. doi: 10.1016/j.jorganchem.2012.04.013
  • Synthesis, characterization and ethylene oligomerization behaviour of N-(2-alkyl-5,6,7-trihydroquinolin-8-ylidene)arylaminonickel(II) dichlorides, W. B. Chai, J. G. Yu, L. Wang, X. Q. Hu, C. Redshaw, and W. H. Sun, Inorg. Chim. Acta, 2012, 385, 21-6. doi: 10.1016/j.ica.2011.12.008
  • 2-[1-(2,6-Dibenzhydryl-4-chlorophenylimino)ethyl]-6-[1-(arylimino)ethyl] pyridyliron(II) dichlorides: Synthesis, characterization and ethylene polymerization behaviour, X. P. Cao, F. He, W. Z. Zhao, Z. G. Cai, X. Hao, T. Shiono, C. Redshaw, and W. H. Sun, Polymer, 2012, 53, 1870-80. doi: 10.1016/j.polymer.2012.02.050
  • 2,6-Dibenzhydryl-N-(2-aryliminoacenaphthylenylidene)-4-chlorobenzenamino palladium dichlorides: Synthesis, characterization, and use as catalysts in the Heck-reaction, Q. Ban, J. Zhang, T. L. Liang, C. Redshaw, and W. H. Sun, J. Organomet. Chem., 2012, 713, 151-6. doi: 10.1016/j.jorganchem.2012.05.015

2011

  • 2-(N-Alkylcarboxamide)-6-iminopyridyl palladium and nickel complexes: coordination chemistry and catalysis, W. J. Zhang, Y. H. Wang, J. G. Yu, C. Redshaw, X. Hao, and W. H. Sun, Dalton Trans., 2011, 40, 12856-65. doi: 10.1039/c1dt11079a
  • Synthesis and Characterization of Dialkylaluminum Amidates and Their Ring-Opening Polymerization of epsilon-Caprolactone, W. J. Zhang, Y. H. Wang, J. Cao, L. Wang, Y. Pan, C. Redshaw, and W. H. Sun, Organometallics, 2011, 30, 6253-61. doi: 10.1021/om2008343
  • Synthesis, Characterization, and Ethylene Polymerization Behaviour of 8-(Nitroarylamino)-5,6,7-trihydroquinolylnickel Dichlorides: Influence of the Nitro Group and Impurities on Catalytic Activity, L. P. Zhang, X. Hao, W. H. Sun, and C. Redshaw, ACS Catal., 2011, 1, 1213-20. doi: 10.1021/cs200308b
  • 2-[1-(2,6-Dibenzhydryl-4-methylphenylimino)ethyl]-6-[1-(arylimino)ethyl] -pyridylcobalt(II) dichlorides: Synthesis, characterization and ethylene polymerization behaviour, J. G. Yu, W. Huang, L. Wang, C. Redshaw, and W. H. Sun, Dalton Trans., 2011, 40, 10209-14. doi: 10.1039/c1dt11062d
  • Ferrous and cobaltous chloride complexes bearing 2-(1-(arylimino)methyl)-8-(1H-benzimidazol-2-yl)quinolines: Synthesis, characterization and catalytic behaviour in ethylene polymerization, T. P. F. Xiao, S. Zhang, B. X. Li, X. Hao, C. Redshaw, Y. S. Li, and W. H. Sun, Polymer, 2011, 52, 5803-10. doi: 10.1016/j.polymer.2011.10.037
  • Synthesis and characterization of trichlorotitanium 2-(2-pyridinyliminomethyl)phenolates and their ethylene (co-)polymerization behaviour, Y. H. Wang, W. J. Zhang, W. Huang, L. Wang, C. Redshaw, and W. H. Sun, Polymer, 2011, 52, 3732-7. doi: 10.1016/j.polymer.2011.06.036
  • 2-Benzimidazolyl-N-phenylquinoline-8-carboxamide Chromium(III) Trichlorides: Synthesis and Application for Ethylene Oligomerization and Polymerization, D. Wang, S. F. Liu, Y. N. Zeng, W. H. Sun, and C. Redshaw, Organometallics, 2011, 30, 3001-9. doi: 10.1021/om2001124
  • Methylaluminium 8-quinolinolates: synthesis, characterization and use in ring-opening polymerization (ROP) of epsilon-caprolactone, W. H. Sun, M. A. Shen, W. J. Zhang, W. Huang, S. F. Liu, and C. Redshaw, Dalton Trans., 2011, 40, 2645-53. doi: 10.1039/c0dt01207f
  • Synthesis, characterization and catalytic behaviour toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines, S. J. Song, W. Z. Zhao, L. Wang, C. Redshaw, F. S. Wang, and W. H. Sun, J. Organomet. Chem., 2011, 696, 3029-35. doi: 10.1016/j.jorganchem.2011.06.003
  • Iron(II) and cobalt(II) complexes bearing 8-(1-aryliminoethylidene) quinaldines: Synthesis, characterization and ethylene dimerization behaviour, S. J. Song, T. P. F. Xiao, C. Redshaw, X. Hao, F. S. Wang, and W. H. Sun, J. Organomet. Chem., 2011, 696, 2594-9. doi: 10.1016/j.jorganchem.2011.03.039
  • Synthesis, characterization and ethylene oligomerization behaviour of 8-(1-aryliminoethylidene)quinaldinylnickel dihalides, S. J. Song, T. P. F. Xiao, T. L. Liang, F. S. Wang, C. Redshaw, and W. H. Sun, Catal. Sci. Technol., 2011, 1, 69-75. doi: 10.1039/c0cy00002g
  • 2-(1-Aryliminoethylidene)quinolylnickel(II) dibromides: Synthesis, characterization and ethylene dimerization capability, S. J. Song, Y. Li, C. Redshaw, F. S. Wang, and W. H. Sun, J. Organomet. Chem., 2011, 696, 3772-8. doi: 10.1016/j.jorganchem.2011.08.037
  • Ethylene Polymerization Catalysis by Vanadium-Based Systems Bearing Sulfur-Bridged Calixarenes, C. Redshaw, L. Clowes, D. L. Hughes, M. R. J. Elsegood, and T. Yamato, Organometallics, 2011, 30, 5620-4. doi: 10.1021/om200402u
  • Synthesis and evaluation of a novel pyrenyl-appended triazole-based thiacalix[4]arene as a fluorescent sensor for Ag+ ion, X. L. Ni, X. Zeng, C. Redshaw, and T. Yamato, Tetrahedron, 2011, 67, 3248-53. doi: 10.1016/j.tet.2011.03.008
  • Ratiometric Fluorescent Receptors for Both Zn2+ and H2PO4- Ions Based on a Pyrenyl-Linked Triazole-Modified Homooxacalix[3]arene: A Potential Molecular Traffic Signal with an R-S Latch Logic Circuit, X. L. Ni, X. Zeng, C. Redshaw, and T. Yamato, J. Org. Chem., 2011, 76, 5696-702. doi: 10.1021/jo2007303
  • Synthesis, crystal structure and complexation behaviour of a thiacalix[4]arene bearing 1,2,3-triazole groups, X. L. Ni, X. Zeng, D. L. Hughes, C. Redshaw, and T. Yamato, Supramol. Chem., 2011, 23, 689-95. doi: 10.1080/10610278.2011.601603
  • Novel ion-pair receptors based on hexahomotrioxacalix[3]arene derivatives, X. L. Ni, S. Rahman, X. Zeng, D. L. Hughes, C. Redshaw, and T. Yamato, Org. Biomol. Chem., 2011, 9, 6535-41. doi: 10.1039/c1ob05564j
  • Amine influence in vanadium-based ethylene polymerisation pro-catalysts bearing bis(phenolate) ligands with 'pendant' arms, C. Lorber, E. Despagnet-Ayoub, L. Vendier, A. Arbaoui, and C. Redshaw, Catal. Sci. Technol., 2011, 1, 489-94. doi: 10.1039/c1cy00089f
  • 2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenami ne Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization, H. Liu, W. Z. Zhao, X. A. Hao, C. Redshaw, W. Huang, and W. H. Sun, Organometallics, 2011, 30, 2418-24. doi: 10.1021/om200154a
  • Synthesis, characterization and ethylene oligomerization behaviour of 2-benzoimidazol-8-ethoxyquinolylnickel dihalides, H. Liu, L. P. Zhang, L. Q. Chen, C. Redshaw, Y. Li, and W. H. Sun, Dalton Trans., 2011, 40, 2614-21. doi: 10.1039/c0dt01331e
  • 2-(1-(Arylimino)propyl)quinolin-8-olate half-titanocene dichlorides: Synthesis, characterization and ethylene (co-)polymerization behaviour, W. Huang, W. H. Sun, and C. Redshaw, Dalton Trans., 2011, 40, 6802-9. doi: 10.1039/c1dt10068h
  • Synthesis, characterization and ethylene (co-)polymerization behaviour of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides, W. Huang, B. X. Li, Y. H. Wang, W. J. Zhang, L. Wang, Y. S. Li, W. H. Sun, and C. Redshaw, Catal. Sci. Technol., 2011, 1, 1208-15. doi: 10.1039/c1cy00193k
  • Vanadium-Based Pro-Catalysts Bearing Depleted 1,3-Calix[4]arenes for Ethylene or epsilon-Caprolactone Polymerization, L. Clowes, C. Redshaw, and D. L. Hughes, Inorg. Chem., 2011, 50, 7838-45. doi: 10.1021/ic2010198
  • Bimetallic copper(II) and zinc(II) complexes of acyclic Schiff base ligands derived from amino acids, A. Arbaoui, C. Redshaw, N. M. Sanchez-Ballester, M. R. J. Elsegood, and D. L. Hughes, Inorg. Chim. Acta, 2011, 365, 96-102. doi: 10.1016/j.ica.2010.08.043

2010

  • Synthesis and characterisation of alkylaluminium benzimidazolates and their use in the ring-opening polymerisation of epsilon-caprolactone, M. A. Shen, W. Huang, W. J. Zhang, X. A. Hao, W. H. Sun, and C. Redshaw, Dalton Trans., 2010, 39, 9912-22. doi: 10.1039/c0dt00514b
  • Enhancement of H-2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters, C. Redshaw, S. Jana, C. X. Shang, M. R. J. Elsegood, X. S. Lu, and Z. X. Guo, Chem. Commun., 2010, 46, 9055-7. doi: 10.1039/c0cc03380d
  • Multinuclear Zinc Pentafluorobenzene Carboxylates: Synthesis, Characterization, and Hydrogen Storage Capability, C. Redshaw, S. Jana, C. X. Shang, M. R. J. Elsegood, X. S. Lu, and Z. X. Guo, Organometallics, 2010, 29, 6129-32. doi: 10.1021/om100703c
  • Vanadium procatalysts bearing chelating aryloxides: structure-activity trends in ethylene polymerisation, C. Redshaw, Dalton Trans., 2010, 39, 5595-604. doi: 10.1039/b924088h
  • Synthesis, structures and luminescent behaviour of tridentate salicylaldiminato-type borate complexes, V. Christou, S. E. Watkins, R. McCann, C. Redshaw, and M. R. J. Elsegood, Inorg. Chim. Acta, 2010, 363, 1173-8. doi: 10.1016/j.ica.2009.11.006
  • Iron(III) and Zinc(II) Calixarene Complexes: Synthesis, Structural Studies, and Use as Procatalysts for epsilon-Caprolactone Polymerization, A. Arbaoui, C. Redshaw, M. R. J. Elsegood, V. E. Wright, A. Yoshizawa, and T. Yamato, Chem.-Asian J., 2010, 5, 621-33. doi: 10.1002/asia.200900514
  • Metal catalysts for epsilon-caprolactone polymerisation, A. Arbaoui and C. Redshaw, Polym. Chem., 2010, 1, 801-26. doi: 10.1039/b9py00334g

2009

  • Hydrogen bonding receptors of tetraamide derivatives derived from thiacalix[4]arene in cone- and 1,3-alternate conformation, T. Yamato, C. Perez-Casas, A. Yoshizawa, S. Rahman, M. R. J. Elsegood, and C. Redshaw, J. Incl. Phenom. Macrocycl. Chem., 2009, 63, 301-8. doi: 10.1007/s10847-008-9523-4
  • EPR Monitoring of Vanadium(IV) Species Formed upon Activation of Vanadium(V) Polyphenolate Precatalysts with AlR2Cl and AlR2Cl/Ethyltrichloroacetate (R = Me, Et), I. E. Soshnikov, N. V. Semikolenova, A. A. Shubin, K. P. Bryliakov, V. A. Zakharov, C. Redshaw, and E. P. Talsi, Organometallics, 2009, 28, 6714-20. doi: 10.1021/om900515h
  • Investigating the Nature of the Active Species in Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts, I. E. Soshnikov, N. V. Semikolenova, A. N. Bushmelev, K. P. Bryliakov, O. V. Lyakin, C. Redshaw, V. A. Zakharov, and E. P. Talsi, Organometallics, 2009, 28, 6003-13. doi: 10.1021/om900490b
  • An EPR study of the vanadium species formed upon interaction of vanadyl N and C-capped tris(phenolate) complexes with AlEt3 and AlEt2Cl, I. E. Soshnikov, N. V. Semikolenova, K. P. Bryliakov, V. A. Zakharov, C. Redshaw, and E. P. Talsi, J. Mol. Catal. A-Chem., 2009, 303, 23-9. doi: 10.1016/j.molcata.2008.12.013
  • An EPR Study of the V(IV) Species Formed Upon Activation of a Vanadyl Phenoxyimine Polymerization Catalyst with AlR3 and AlR2Cl (R = Me, Et), I. E. Soshnikov, N. V. Semikolenova, K. P. Bryliakov, A. A. Shubin, V. A. Zakharov, C. Redshaw, and E. P. Talsi, Macromol. Chem. Phys., 2009, 210, 542-8. doi: 10.1002/macp.200800556
  • New structural motifs in chromium(III) calix[4 and 6]arene chemistry, C. Redshaw, D. Homden, D. L. Hughes, J. A. Wright, and M. R. J. Elsegood, Dalton Trans., 2009, 1231-42. doi: 10.1039/b813313a
  • Two related lithium calixarene complexes, [p-tert-butylcalix[4]arene(OMe)(OH)(2)(OLi)](2)center dot 4MeCN and {p-tert-butylcalix[4]arene (OH)(2)(OLi)[OLi(NCMe)(2)]}(2)center dot 8MeCN, determined using synchrotron radiation, D. S. Lee, M. R. J. Elsegood, C. Redshaw, and S. Z. Zhan, Acta Crystallogr. Sect. C-Cryst. Struct. Commun., 2009, 65, M291-M5. doi: 10.1107/s0108270109025311
  • Synthesis, structure and ethylene polymerisation behaviour of vanadium(IV and V) complexes bearing chelating aryloxides, D. Homden, C. Redshaw, L. Warford, D. L. Hughes, J. A. Wright, S. H. Dale, and M. R. J. Elsegood, Dalton Trans., 2009, 8900-10. doi: 10.1039/b901810g
  • 2-Benzoxazolyl-6-(1-(arylimino)ethyl)pyridyl cobalt (II) chlorides: A temperature switch catalyst in oligomerization and polymerization of ethylene, R. Gao, K. F. Wang, Y. Li, F. S. Wang, W. H. Sun, C. Redshaw, and M. Bochmann, J. Mol. Catal. A-Chem., 2009, 309, 166-71. doi: 10.1016/j.molcata.2009.05.021
  • Arylboron complexes of the acids Ph2C(XH)CO2H (X = O, NH), A. Arbaoui, C. Redshaw, D. L. Hughes, and M. R. J. Elsegood, Inorg. Chim. Acta, 2009, 362, 509-14. doi: 10.1016/j.ica.2008.04.050
  • One-pot conversion of tetraiminodiphenols to diiminodiaminodiphenols via methyl transfer at aluminium, A. Arbaoui, C. Redshaw, and D. L. Hughes, Supramol. Chem., 2009, 21, 35-43. doi: 10.1080/10610270802438846
  • Vanadium-based imido-alkoxide pro-catalysts bearing bisphenolate ligands for ethylene and epsilon-caprolactone polymerisation, A. Arbaoui, C. Redshaw, D. M. Homden, J. A. Wright, and M. R. J. Elsegood, Dalton Trans., 2009, 8911-22. doi: 10.1039/b902402f

2008

  • Low biodegradability of fluoxetine HCl, diazepam and their human metabolites in sewage sludge-amended soil, C. H. Redshaw, M. P. Cooke, H. M. Talbot, S. McGrath, and S. J. Rowland, J. Soils Sediments, 2008, 8, 217-30. doi: 10.1007/s11368-008-0024-2
  • Bis(imido) rhenium complexes bearing C- or N-capped 'tripodal' ligands: Bi- versus tri-dentate ligation, C. Redshaw, S. Z. Zhan, S. H. Dale, and M. R. J. Elsegood, Inorg. Chem. Commun., 2008, 11, 754-6. doi: 10.1016/j.inoche.2008.03.020
  • Rhenium calix[4]arenes: Precursors to novel imaging and cancer therapy agents, C. Redshaw, X. M. Liu, S. Z. Zhan, D. L. Hughes, H. Baillie-Johnson, M. R. J. Elsegood, and S. H. Dale, Eur. J. Inorg. Chem., 2008, 2698-712. doi: 10.1002/ejic.200800275
  • Cellular uptake of a fluorescent calix[4]arene derivative, R. Lalor, H. Baillie-Johnson, C. Redshaw, S. E. Matthews, and A. Mueller, J. Am. Chem. Soc., 2008, 130, 2892-3. doi: 10.1021/ja0782596
  • The Use of Calixarenes in Metal-Based Catalysis, D. M. Homden and C. Redshaw, Chem. Rev., 2008, 108, 5086-130. doi: 10.1021/cr8002196
  • Early transition metal complexes bearing a C-capped tris(phenolate) ligand incorporating a pendant imine arm: Synthesis, structure, and ethylene polymerization behaviour, D. Homden, C. Redshaw, J. A. Wright, D. L. Hughes, and M. R. J. Elsegood, Inorg. Chem., 2008, 47, 5799-814. doi: 10.1021/ic702506w
  • Alkylzinc hydrazides: Self-assembly of hexanuclear ring systems in acetonitrile, M. R. J. Elsegood and C. Redshaw, Chem.-Eur. J., 2008, 14, 3530-4. doi: 10.1002/chem.200800183
  • Mounting a hydrogenase analog on calixarenes - designing a nature-inspired solid state catalyst for fuel cells by density functional theory, E. S. Dy, H. Kasai, C. Redshaw, and C. J. Pickett, Surf. Interface Anal., 2008, 40, 1092-7. doi: 10.1002/sia.2850
  • Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of epsilon-caprolactone, A. Arbaoui, C. Redshaw, and D. L. Hughes, Chem. Commun., 2008, 4717-9. doi: 10.1039/b810417d

2007

  • Synthesis and structure of a 1,3-alternate-thiacalix[4]arene diamide derivative, T. Yamato, C. Perez-Casas, S. Rahman, Z. Xi, M. R. J. Elsegood, and C. Redshaw, J. Incl. Phenom. Macrocycl. Chem., 2007, 58, 193-7. doi: 10.1007/s10847-006-9144-8
  • Synthesis and structure of pentamethylcyclopentadienyl tungsten(V) complexes containing functionalized 6,12-epiiminodibenzo[b,f][1.5]diazocine ligands, C. Redshaw, P. T. Wood, and M. R. J. Elsegood, Organometallics, 2007, 26, 6501-4. doi: 10.1021/om700810p
  • Oxo- and imidovanadium complexes incorporating methylene- and dimethyleneoxa-bridged calix[3]- and -[4]arenes: Synthesis, structures and ethylene polymerisation catalysis, C. Redshaw, M. A. Rowan, L. Warford, D. M. Homden, A. Arbaoui, M. R. J. Elsegood, S. H. Dale, T. Yamato, C. P. Casas, S. Matsui, and S. Matsuura, Chem.-Eur. J., 2007, 13, 1090-107. doi: 10.1002/chem.200600679
  • Niobium- and tantalum-based ethylene polymerisation catalysts bearing methylene- or dimethyleneoxa-bridged calixarene ligands, C. Redshaw, M. Rowan, D. M. Homden, M. R. L. Elsegood, T. Yamato, and C. Perez-Casas, Chem.-Eur. J., 2007, 13, 10129-39. doi: 10.1002/chem.200700893
  • Niobium and tantalum based ethylene polymerization catalysts bearing methylene or dimethyleneoxa bridged calixarene ligands, C. Redshaw, M. Rowan, D. M. Homden, M. R. J. Elsegood, T. Yamato, and C. P. Casas, Abstr. Pap. Am. Chem. Soc., 2007, 233, 207-. doi:
  • New coordination modes at molybdenum for 2-diphenylphosphinoaniline derived ligands, C. Redshaw, V. C. Gibson, M. R. J. Elsegood, and W. Clegg, Chem. Commun., 2007, 1951-3. doi: 10.1039/b700158d
  • Synthesis of tetra-, hexa-, and octanuclear organozinc ring systems, C. Redshaw and M. R. J. Elsegood, Angew. Chem. Int. Edit., 2007, 46, 7453-7. doi: 10.1002/anie.200702562
  • Coordination chemistry of calix[6 and 8]arenes, C. Redshaw and M. R. J. Elsegood, Abstr. Pap. Am. Chem. Soc., 2007, 233, 351-. doi:
  • Vanadium complexes possessing N2O2S2 based ligands as highly active pro-catalysts for the homo-polymerization of ethylene and co-polymerization of ethylene/1-hexene, D. M. Homden, C. Redshaw, and D. L. Hughes, Abstr. Pap. Am. Chem. Soc., 2007, 233, 206-. doi:
  • Vanadium complexes possessing N2O2S2-based ligands: Highly active procatalysts for the homopolymerization of ethylene and copolymerization of ethylene/1-hexene, D. M. Homden, C. Redshaw, and D. L. Hughes, Inorg. Chem., 2007, 46, 10827-39. doi: 10.1021/ic701461b
  • Aluminum alkyl-mediated route to novel N,N,O-chelates for five-coordinate iron(II) chloride complexes: Synthesis, structures, and ethylene polymerization studies, V. C. Gibson, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williarns, Organometallics, 2007, 26, 5119-23. doi: 10.1021/om700611q
  • Bis(imino)pyridines: Surprisingly reactive ligands and a gateway to new families of catalysts, V. C. Gibson, C. Redshaw, and G. A. Solan, Chem. Rev., 2007, 107, 1745-76. doi: 10.1021/cr068437y
  • 'Electronic bending' of imido ligands and the effect on the coordination mode of a tridentate ancillary ligand, V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, Polyhedron, 2007, 26, 3161-7. doi: 10.1016/j.poly.2007.02.008
  • Triarylboron adducts of "magic" carboxylic acids: Structures and luminescent properties, A. Arbaoui, C. Redshaw, M. R. J. Elsegood, D. L. Hughes, and M. Green, Abstr. Pap. Am. Chem. Soc., 2007, 233, 210-. doi:

2006

  • Regioselective synthesis and inclusion properties of distal-bis[(2-pyridylmethyl) oxy]tetrathiacalix[4]arenes, T. Yamato, C. P. Casas, H. Yamamoto, M. R. J. Elsegood, S. H. Dale, and C. Redshaw, J. Incl. Phenom. Macrocycl. Chem., 2006, 54, 261-9. doi: 10.1007/s10847-005-8649-x
  • Synthesis, structures and inclusion properties of distal-bis-[(2-pyridylmethyl)oxy]tetrathiacalix[4]arenes, T. Yamato, C. P. Casas, S. Rahman, J. T. Gil, M. R. J. Elsegood, and C. Redshaw, J. Chem. Res.-S, 2006, 270-3. doi:
  • Synthesis and inclusion properties of a novel thiacalix[4]arene-based hard-soft receptor with 1,3-alternate conformation, T. Yamato, C. P. Casas, M. R. J. Elsegood, S. H. Dale, and C. Redshaw, J. Incl. Phenom. Macrocycl. Chem., 2006, 55, 31-6. doi: 10.1007/s10847-005-9014-9
  • Vanadyl C and N-capped tris(phenolate) complexes: influence of procatalyst geometry on catalytic activity, C. Redshaw, M. A. Rowan, D. M. Homden, S. H. Dale, M. R. J. Elsegood, S. Matsui, and S. Matsuura, Chem. Commun., 2006, 3329-31. doi: 10.1039/b606897a
  • Complexes of tungsten(IV,VI) derived from linked aryloxide ligands, C. Redshaw and S. M. Humphrey, Polyhedron, 2006, 25, 1946-54. doi: 10.1016/j.poly.2005.12.008
  • Synthesis and disruption of a tetrametallic zinc hydrazide, C. Redshaw and M. R. J. Elsegood, Chem. Commun., 2006, 523-5. doi: 10.1039/b516431a
  • Chromogenic indicator for anion reporting based on an N-substituted oxoporphyrinogen, J. P. Hill, A. L. Schumacher, F. D'Souza, J. Labuta, C. Redshaw, M. R. J. Elsegood, M. Aoyagi, T. Nakanishi, and K. Ariga, Inorg. Chem., 2006, 45, 8288-96. doi: 10.1021/ic0611591

2005

  • Niobium-based ethylene polymerization procatalysts bearing di- and triphenolate ligands, C. Redshaw, D. M. Homden, M. A. Rowan, and M. R. J. Elsegood, Inorg. Chim. Acta, 2005, 358, 4067-74. doi: 10.1016/j.ica.2005.05.013
  • Synthesis of hexa- and dodecanuclear organoaluminum ring structures incorporating the "magic" Ph2C(X) Group (X = O-, NH-), C. Redshaw, M. R. J. Elsegood, and K. E. Holmes, Angew. Chem. Int. Edit., 2005, 44, 1850-3. doi: 10.1002/anie.200461627
  • Synthesis of bis(bora) calix[4]arenes bearing perfluoroaryl substituents, C. Redshaw and M. R. J. Elsegood, Chem. Commun., 2005, 5056-8. doi: 10.1039/b509556e
  • Acid/amide bonding for anthranilic acid derivatives: crystal structures of [W(X)Cl-3(HO2CC6H4NH-2)] (X = O, NPh), S. M. Humphrey, C. Redshaw, K. E. Holmes, and M. R. J. Elsegood, Inorg. Chim. Acta, 2005, 358, 222-6. doi: 10.1016/j.ica.2004.07.042
  • Variable solid state aggregations in a series of (isocyanide)gold(I) halides with the novel trimethylamine-isocyanoborane adduct, S. M. Humphrey, H. G. Mack, C. Redshaw, M. R. J. Elsegood, K. J. H. Young, H. A. Mayer, and W. C. Kaska, Dalton Trans., 2005, 439-46. doi: 10.1039/b416392c

2004

  • Vanadyl complexes bearing bi- and triphenolate chelate ligands: highly active ethylene polymerisation procatalysts, C. Redshaw, L. Warford, S. H. Dale, and M. R. J. Elsegood, Chem. Commun., 2004, 1954-5. doi: 10.1039/b406783e
  • [{(H3C)(3)NB(H)(2)NC}(2)Au][AuI2]: a linear chain polymer of gold(I) iodide with an unusual isocyanoborane ligand showing aurophilic behaviour, W. C. Kaska, H. A. Mayer, M. R. J. Elsegood, P. N. Horton, M. B. Hursthouse, C. Redshaw, and S. M. Humphrey, Acta Crystallogr. Sect. E.-Struct Rep. Online, 2004, 60, M563-M5. doi: 10.1107/s1600536804008098
  • Synthesis, characterization and reactivity of the molybdenum(VI) complex [MoCl(NAr)(2)(CH2CMe2Ph)] (Ar=2,6-(Pr2C6H3)-C-i), V. C. Gibson, C. Redshaw, G. L. P. Walker, W. Clegg, and M. R. Elsegood, J. Organomet. Chem., 2004, 689, 332-44. doi: 10.1016/j.jorganchem.2003.10.020
  • Synthesis and X-ray crystal structures of hydridotris(3,5-dimethylpyrazolyl)borate (Tp ') molybdenum(VI) bis(imido) complexes, V. C. Gibson, C. Redshaw, W. Clegg, M. R. J. Elsegood, U. Siemeling, and T. Turk, Polyhedron, 2004, 23, 189-94. doi: 10.1016/j.poly.2003.10.005
  • Synthesis and X-ray crystal structures of hydridotris (3,5 -dimethylpyrazolyl)borate (Tp ') molybdenum(VI) bis(imido) complexes (vol 23, pg 189, 2004), V. C. Gibson, C. Redshaw, W. Clegg, M. R. J. Elsegood, U. Siemeling, and T. Turk, Polyhedron, 2004, 23, 1291-. doi: 10.1016/j.poly.2003.09.038
  • Bis(imino)phenoxide complexes of aluminium, V. C. Gibson, D. Nienhuis, C. Redshaw, A. J. P. White, and D. J. Williams, Dalton Trans., 2004, 1761-5. doi: 10.1038/b403752a

2003

  • Tungsten(VI) complexes derived from calix[6]- and -[8]arenes: Oxo and oxychloride species, C. Redshaw and M. R. J. Elsegood, Eur. J. Inorg. Chem., 2003, 2071-4. doi:
  • Coordination chemistry of the larger calixarenes, C. Redshaw, Coord. Chem. Rev., 2003, 244, 45-70. doi: 10.1016/s0010-8545(03)00099-7
  • Low valent chromium complexes bearing N,O-chelating pyridylenolate ligands [OC(Bu-t)(= 2-CHN5H3Me-x)](-) (x=3-6), V. C. Gibson, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, Dalton Trans., 2003, 4612-7. doi: 10.1039/b308881m
  • From monomeric to polymeric manganese complexes bearing bis(imino)pyridine and related ligands, V. C. Gibson, S. McTavish, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, Dalton Trans., 2003, 221-6. doi: 10.1039/b207384f
  • Polymorphism and pseudopolymorphism in calixarenes: acetonitrile clathrates of p-Bu-t-calix[n]arenes (n = 6 and 8), S. H. Dale, M. R. J. Elsegood, and C. Redshaw, Crystengcomm, 2003, 5, 368-73. doi: 10.1039/b308407h

2002

  • A novel ligand family based on bulky metallocalix[4 and 8] arene substituents, V. C. Gibson, C. Redshaw, and M. R. J. Elsegood, New J. Chem., 2002, 26, 16-9. doi: 10.1039/b108088c
  • Novel tungsten calix[8]arene complexes, V. C. Gibson, C. Redshaw, and M. R. J. Elsegood, Chem. Commun., 2002, 1200-1. doi: 10.1039/b201777f
  • Chromium complexes bearing pyrrolide-imine N,N-chelate ligands: synthesis, structures and ethylene polymerisation behaviour, V. C. Gibson, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 2002, 4017-23. doi: 10.1039/b204568k
  • Synthesis and characterisation of neutral and cationic alkyl aluminium complexes bearing N,O-Schiff base chelates with pendant donor arms, P. A. Cameron, V. C. Gibson, C. Redshaw, J. A. Segal, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 2002, 415-22. doi: 10.1039/b106131n

2001

  • Dimetallocalix[8]arene complexes bearing pendant amino and Schiff-base groups, C. Redshaw and M. R. J. Elsegood, Abstr. Pap. Am. Chem. Soc., 2001, 221, U669-U. doi:
  • Novel organoaluminium (and gallium) carboxylate-bridged ring systems, C. Redshaw and M. R. J. Elsegood, Chem. Commun., 2001, 2016-7. doi: 10.1039/b106113p
  • Synthesis and structural characterisation of [Mo(NNPh2)(NPh2)(mesityl)(2)(OC6F5)] and {[W(NNPh2)(NPh2)(OSiMe3)](2)(mu-Cl)(2)(mu-O)}: isodiazene complexes with bulky amide groups arising via N-N bond cleavage, C. Redshaw, W. Clegg, and M. R. J. Elsegood, Polyhedron, 2001, 20, 119-23. doi: 10.1016/s0277-5387(00)00606-9
  • Aluminium-containing ring systems and N-heterocycle formation via nitrile insertions into Al-N bonds, V. C. Gibson, C. Redshaw, A. J. P. White, and D. J. Williams, Chem. Commun., 2001, 79-80. doi: 10.1039/b007810g
  • Calix[6] and [8]arene complexes of vanadium, V. C. Gibson, C. Redshaw, and M. R. J. Elsegood, J. Chem. Soc., Dalton Trans., 2001, 767-9. doi: 10.1039/b010248m
  • Carboxylate versus imidobenzoate bonding for anthranilic acid derivatives. Crystal structures of [W(eta-C5Me5)Cl-3(eta(2)-O2CC6H4NH2-2)] and [ReCl(OEt)(PPh3)(2) (NC6H4CO2)], V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, Inorg. Chem. Commun., 2001, 4, 95-9. doi: 10.1016/s1387-7003(00)00216-1
  • Synthesis, structures and ethylene polymerisation behaviour of low valent beta-diketiminato chromium complexes, V. C. Gibson, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, Eur. J. Inorg. Chem., 2001, 1895-903. doi:
  • Synthesis and characterisation of neutral dialkylaluminium complexes stabilised by salicylaldiminato ligands, and their conversion to monoalkylaluminium cations, P. A. Cameron, V. C. Gibson, C. Redshaw, J. A. Segal, G. A. Solan, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 2001, 1472-6. doi: 10.1039/b100743m
  • Imine versus amine donors in iron-based ethylene polymerisation catalysts, G. J. P. Britovsek, V. C. Gibson, S. Mastroianni, D. C. H. Oakes, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, Eur. J. Inorg. Chem., 2001, 431-7. doi:
  • Bis(imino)pyridyl iron and cobalt complexes: the effect of nitrogen substituents on ethylene oligomerisation and polymerisation, G. J. P. Britovsek, V. C. Gibson, B. S. Kimberley, S. Mastroianni, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 2001, 1639-44. doi: 10.1039/b101173l

2000

  • Group 6 metallocalixarenes bearing "hydrazido(2-)" groups, C. Redshaw and M. R. J. Elsegood, Inorg. Chem., 2000, 39, 5164-8. doi: 10.1021/ic000098i
  • Synthesis and structure of a novel molybdenum imido calix[6]arene, C. Redshaw and M. R. J. Elsegood, Polyhedron, 2000, 19, 2657-9. doi: 10.1016/s0277-5387(00)00579-9
  • A five-coordinate chromium alkyl complex stabilised by salicylaldiminato ligands, V. C. Gibson, S. Mastroianni, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 2000, 1969-71. doi: 10.1039/b002631j
  • Oligomerisation of ethylene by bis(imino)pyridyliron and cobalt complexes, G. J. P. Britovsek, S. Mastroianni, G. A. Solan, S. P. D. Baugh, C. Redshaw, V. C. Gibson, A. J. P. White, D. J. Williams, and M. R. J. Elsegood, Chem.-Eur. J., 2000, 6, 2221-31. doi: 10.1002/1521-3765(20000616)6:12<2221::aid-chem2221>3.3.co;2-l

1999

  • Novel aluminum-containing ring systems: An octanuclear structural analogue of a calix[4]pyrrole, V. C. Gibson, C. Redshaw, A. J. P. White, and D. J. Williams, Angew. Chem. Int. Edit., 1999, 38, 961-4. doi: 10.1002/(sici)1521-3773(19990401)38:7<961::aid-anie961>3.0.co;2-#
  • Synthesis, characterisation and reactivity of the molybdenum(VI) dimethyl complex [Mo(NR)(2)Me-2] (R = 2,6-(Pr2C6H3)-C-i), V. C. Gibson, C. Redshaw, G. L. P. Walker, J. A. K. Howard, V. J. Hoy, J. M. Cole, L. G. Kuzmina, and D. S. De Silva, J. Chem. Soc., Dalton Trans., 1999, 161-5. doi: 10.1039/a806171h
  • Chromium ethylene polymerisation catalysts bearing reduced Schiff-base N,O-chelate ligands, V. C. Gibson, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 1999, 827-9. doi: 10.1039/a900118b
  • Molybdenum and tungsten mono-isodiazene complexes with alkyl ligands as ring-opening metathesis polymerisation procatalysts. Crystal and molecular structures of [Mo(CH2CMe2Ph)(3)(NNPh2)(OC6F5)], [W(CH2SiMe3)(3)(NNPh2)(OC6F5)] and [WCl2(NNPh2)(OC6F5)(2)(thf)], J. R. Dilworth, V. C. Gibson, C. Redshaw, A. J. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 1999, 2701-4. doi: 10.1039/a903770e
  • Bis(isodiazene) and related complexes of molybdenum(VI). Syntheses and structures of [Mo(OTf)(2)(NNPh2)(2)(py)(2)], [MoCl(OTf)(NNPh2){NC5H3(CH2C(O)Ph-2)(2)-2,6}], [{MoCl(NNPh2)(2)(mu-Cl)(NH2But)}(2)] and [MoTp ' Cl(NNPh2)(2)] [OTf = O3SCF3, Tp ' = tris(3,5-dimethylpyrazolyl)hydroborate], J. R. Dilworth, V. C. Gibson, N. Davies, C. Redshaw, A. P. White, and D. J. Williams, J. Chem. Soc., Dalton Trans., 1999, 2695-9. doi: 10.1039/a903372f
  • Pendant arm Schiff base complexes of aluminium as ethylene polymerisation catalysts, P. A. Cameron, V. C. Gibson, C. Redshaw, J. A. Segal, M. D. Bruce, A. J. P. White, and D. J. Williams, Chem. Commun., 1999, 1883-4. doi: 10.1039/a905120a
  • Iron and cobalt ethylene polymerization catalysts bearing 2,6-bis(imino)pyridyl ligands: Synthesis, structures, and polymerization studies, G. J. P. Britovsek, M. Bruce, V. C. Gibson, B. S. Kimberley, P. J. Maddox, S. Mastroianni, S. J. McTavish, C. Redshaw, G. A. Solan, S. Stromberg, A. J. P. White, and D. J. Williams, J. Am. Chem. Soc., 1999, 121, 8728-40. doi: 10.1021/ja990449w

1998

  • Benefits of the chelate effect: Preparation of an unsymmetrical ansa-bis(imido)molybdenum complex containing a seven-membered chelate ring, U. Siemeling, T. Turk, W. W. Schoeller, C. Redshaw, and V. C. Gibson, Inorg. Chem., 1998, 37, 4738-9. doi: 10.1021/ic9800381
  • Synthesis and structural characterisation of aluminium imino-amide and pyridyl-amide complexes: bulky monoanionic N,N chelate ligands via methyl group transfer, V. C. Gibson, C. Redshaw, A. J. P. White, and D. J. Williams, J. Organomet. Chem., 1998, 550, 453-6. doi: 10.1016/s0022-328x(97)00552-4
  • Supramolecular metallocalixarene chemistry: linking metallocalixarenes through imido bridges, V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, Chem. Commun., 1998, 1969-70. doi: 10.1039/a801808a
  • Chromium(III) complexes bearing N,N-chelate ligands as ethene polymerization catalysts, V. C. Gibson, P. J. Maddox, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, Chem. Commun., 1998, 1651-2. doi: 10.1039/a802797h
  • A novel titanium-oxygen ladder structure supported by calix[4]arene ligands, characterised by synchrotron crystallography, W. Clegg, M. R. J. Elsegood, S. J. Teat, C. Redshaw, and V. C. Gibson, J. Chem. Soc., Dalton Trans., 1998, 3037-9. doi: 10.1039/a803864c
  • Cationic alkyl aluminium ethylene polymerization catalysts based on monoanionic N,N,N-pyridyliminoamide ligands, M. Bruce, V. C. Gibson, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams, Chem. Commun., 1998, 2523-4. doi: 10.1039/a807950a

1997

  • Pentamethylcyclopentadienyl tungsten complexes containing imido, hydrazido and amino acid derived N-O chelate ligands, C. Redshaw, V. C. Gibson, W. Clegg, A. J. Edwards, and B. Miles, J. Chem. Soc., Dalton Trans., 1997, 3343-7. doi: 10.1039/a703550k
  • Synthesis and structure of bis(methylaluminium center dot NCCH3) p-tert-butylcalix[4]arene, V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, Polyhedron, 1997, 16, 4385-7. doi: 10.1016/s0277-5387(97)00234-9
  • Synthesis and structural characterization of some novel metalloboroxides bearing boron-bound mesityl and fluoromesityl substituents: The molecular structure of the first metallaboroxane complex, V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, Polyhedron, 1997, 16, 2637-41. doi: 10.1016/s0277-5387(96)00601-8
  • Can alkali-metal ions influence the coordination and reactivity of calix[4]arenes at transition-metal centres?, V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, Chem. Commun., 1997, 1605-6. doi: 10.1039/a702272g
  • Synthesis and characterisation of molybdenum complexes bearing highly functionalised imido substituents, V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, J. Chem. Soc., Dalton Trans., 1997, 3207-12. doi: 10.1039/a701502j
  • Bis[hydrazido(2-)] and related complexes of molybdenum(VI): Towards alkene-metathesis catalysts based on hydrazido(2-) ligation, J. R. Dilworth, V. C. Gibson, C. Z. Lu, J. R. Miller, C. Redshaw, and Y. F. Zheng, J. Chem. Soc., Dalton Trans., 1997, 269-72. doi: 10.1039/a606575i
  • Group 6 transition metal complexes containing the sigma-bonded 2,4,6-tris(trifluoromethyl)phenyl(''fluoromes'') ligand, K. B. Dillon, V. C. Gibson, J. A. K. Howard, C. Redshaw, L. Sequeira, and J. W. Yao, J. Organomet. Chem., 1997, 528, 179-83. doi: 10.1016/s0022-328x(96)06700-9

1996

  • Vanadium complexes containing the 2,4,6-tris(trifluoromethyl)phenyl ('fluoromes') ligand, V. C. Gibson, C. Redshaw, L. J. Sequeira, K. B. Dillon, W. Clegg, and M. R. J. Elsegood, Chem. Commun., 1996, 2151-2. doi: 10.1039/cc9960002151
  • Bridged bis(imido)molybdenum complexes: Isolobal analogues of ansa-zirconocenes and bizirconocenes, V. C. Gibson, C. Redshaw, W. Clegg, M. R. J. Elsegood, U. Siemeling, and T. Turk, J. Chem. Soc., Dalton Trans., 1996, 4513-5. doi: 10.1039/dt9960004513
  • Bent versus linear imido ligands in five-co-ordinate molybdenum complexes, V. C. Gibson, E. L. Marshall, C. Redshaw, W. Clegg, and M. R. J. Elsegood, J. Chem. Soc., Dalton Trans., 1996, 4197-9. doi: 10.1039/dt9960004197

1995

  • Novel Metal Imido Calixarene Complexes, V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, J. Chem. Soc., Chem. Commun., 1995, 2371-2. doi: 10.1039/c39950002371

1994

  • Isocyanate Versus Isothiocyanate Insertion into Alkoxo and Imido Ligands, V. C. Gibson, C. Redshaw, W. Clegg, and M. R. J. Elsegood, J. Chem. Soc., Chem. Commun., 1994, 2635-6. doi: 10.1039/c39940002635

1993

  • Complexes of Tungsten(Iv,Vi) and Molybdenum(V) Derived from 1,2-Diaminobenzene - X-Ray Crystal-Structures of Cis,Mer-W(O-Nc6h4nh2)Cl2(Pme3)3, (Wcl[O-(Hn)2c6h4]2(Pme3)2)(Bph4) and Mer,Trans-Mo(O-Nc6h4nh2)Cl3(Pmeph2)2, C. Redshaw, G. Wilkinson, T. K. N. Sweet, and M. B. Hursthouse, Polyhedron, 1993, 12, 2013-9. doi: 10.1016/s0277-5387(00)81475-8
  • Synthesis and X-Ray Crystal-Structure of the Organotungsten(V) O-Phenylene Diamido Complex, (Eta-C5me5)Wcl2(1,2-(Hn)2c6h4), C. Redshaw, G. Wilkinson, T. K. N. Sweet, and M. B. Hursthouse, Polyhedron, 1993, 12, 2417-20. doi: 10.1016/s0277-5387(00)83062-4
  • Synthesis and Characterization of 1,2-Bis(Phosphino)Benzene (Diphos) and Related Complexes of Vanadium, Chromium, Iron and Cobalt - X-Ray Crystal-Structures of Mcl2(Diphos)2 (M = V, Cr and Fe) and [Fe(Diphos)2(Mecn)2](Bph4)2, C. Redshaw, G. Wilkinson, B. Hussainbates, and M. B. Hursthouse, Polyhedron, 1993, 12, 363-70. doi: 10.1016/s0277-5387(00)81739-8
  • Organoimido Complexes of Tungsten - X-Ray Crystal-Structures of W(Nc6h11)Cl2(Pme3)3, [W(Nc6h11)Cl2(Pme3)3]O3scf3, [W(Nc6h11)Cl(Pme3)4]Bph4, W[Nsi(O-Mec6h4)3]Cl2(Pme3)3, W[Nb(Mes2)]2cl2(Pme3)2, (W(Nph)Cl[O2c2(Cf3)4]2)Li and Wcl4(Pme2ph)3, A. A. Danopoulos, C. Redshaw, A. Vaniche, G. Wilkinson, B. Hussainbates, and M. B. Hursthouse, Polyhedron, 1993, 12, 1061-71. doi: 10.1016/s0277-5387(00)87185-5
  • A New Tetratungstate, [W4o4cl10 (Nbu(T)4]2-, and Its Degradation to the Mononuclear Complex [Wocl2(Nbu(T) (Bipy)] or [Wcl2(Nbu(T)2(Bipy)] (Bipy = 2,2'-Bipyridine), W. Clegg, J. Errington, D. C. R. Hockless, and C. Redshaw, J. Chem. Soc., Dalton Trans., 1993, 1965-71. doi: 10.1039/dt9930001965

1992

  • Ortho-Phenylenediamine and Related Complexes of Chromium, Vanadium and Manganese, C. Redshaw, G. Wilkinson, B. Hussainbates, and M. B. Hursthouse, J. Chem. Soc., Dalton Trans., 1992, 1803-11. doi: 10.1039/dt9920001803
  • Interaction of Cyclohexyl Isocyanate with Oxoruthenium(V) 2-Alkyl-2-Hydroxybutyrates, C. Redshaw, W. Clegg, and G. Wilkinson, J. Chem. Soc., Dalton Trans., 1992, 2059-62. doi: 10.1039/dt9920002059
  • Solid-State and Solution Studies of Tungsten(Vi) Organoimidoalkoxides, W. Clegg, R. J. Errington, and C. Redshaw, J. Chem. Soc., Dalton Trans., 1992, 3189-98. doi: 10.1039/dt9920003189
  • Solid-State and Solution Studies of Tungsten(Vi) Oxotetraalkoxides, W. Clegg, R. J. Errington, P. Kraxner, and C. Redshaw, J. Chem. Soc., Dalton Trans., 1992, 1431-8. doi: 10.1039/dt9920001431
  • X-Ray Crystal-Structure of [(Wcl3(Pme2ph)2)2 (Mu-Nc6h4n-1,4)] - the 1st Structural Characterization of a Binuclear Complex Containing a 1,4-Phenylenediimido Bridge, W. Clegg, R. J. Errington, D. C. R. Hockless, J. M. Kirk, and C. Redshaw, Polyhedron, 1992, 11, 381-4. doi: 10.1016/s0277-5387(00)83186-1

1991

  • A Mononuclear Tert-Butylimido Complex of Niobium(V) - X-Ray Crystal-Structure of [Ph3pch2ph][Nb(Nbu(T))Cl4(Py)].Ch2cl2, W. Clegg, R. J. Errington, D. C. R. Hockless, and C. Redshaw, Polyhedron, 1991, 10, 1959-61. doi: 10.1016/s0277-5387(00)86061-1

1989

  • Structure of Unsolvated Benzyltriphenylphosphonium Pentachloro(P-Tolylimido)Tungstate(Vi), W. Clegg, R. J. Errington, and C. Redshaw, Acta Crystallogr. Sect. C-Cryst. Struct. Commun., 1989, 45, 164-5. doi: 10.1107/s0108270188010352
  • Polytungstate Self-Assembly - Structures of the New Oxoanions, [W4(Nbut)4o4cl10]2- and [W6o14cl10]2, W. Clegg, R. J. Errington, D. C. R. Hockless, and C. Redshaw, Polyhedron, 1989, 8, 1788-9. doi: 10.1016/s0277-5387(00)80645-2
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